Innovative Oxidation Team

Oxidation reaction is the most important reaction that dominates over 30% of all chemical processes. However, oxidation typically creates environmentally damaging waste products. An oxidation process, widely applicable from basic chemicals to fine chemicals, is required to use an environmentally benign oxidant.
Our team aims to develop environmentally benign chemical processes by optimizing catalyst for oxidants, such as hydrogen peroxide, which had not been used for industrial production because of low oxidative capability.

Team Leader, Dr. Yoshihiro Kon

Theme

  • Three-Component Catalyst System
  • Sustainable Oxidation Process Using Hydrogen Peroxide
  • Fluorination and related research

Three-Component Catalyst System

Three-Component Catalyst System, the composition of different working three catalysts (the metal complex, the phase transfer catalyst, additional catalyst), enables new efficient selective oxidation using hydrogen peroxide.

Sustainable Oxidation Process Using Hydrogen Peroxide

We have developed various hydrogen peroxide-oxidations by optimizing catalyst system for the substrate. And these oxidations are used as industrial processes.

Fluorination and related research

We have investigated vapor phase fluorination, related synthetic methods, and production of fluoro-chemicals, such as refrigerants and cleaning solvents.

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Members

 April 1, 2020

Position Name Email(*)
Team Leader Yoshihiro Kon y-kon
Principal Research Manager Masanori Tamura m-tamura
Chief Senior Researcher Heng-Dao Quan hengdao-quan
Senior Researcher Dachao Hong

ORCID
Researchmap
hong-d
Researcher Hiroki Nagashima nagashima-hiroki

*Please add “@aist.go.jp” after each local part.

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Results

●Publication List

82) Hydrogen peroxide production from oxygen and formic acid by homogeneous Ir-Ni catalyst.
Yoshihiro Shimoyama, Yuji Ohgomori, Yoshihiro Kon, Dachao Hong
Dalton transactions, 2021, 50(27), 9410-9416.

81) Formate-driven catalysis and mechanism of an iridium-copper complex for selective aerobic oxidation of aromatic olefins in water.
Yoshihiro Shimoyama, Yasutaka Kitagawa, Yuji Ohgomori, Yoshihiro Kon, Dachao Hong
Chemical science 2021, 12(16) 5796-5803.

80) Characterization of functional groups in estuarine dissolved organic matter by DNP-enhanced 15N and 13C solid-state NMR
F. Venel, H. Nagashima, A. G.M. Rankin, C. Anquetil, V. Klimavicius, T. Gutmann, G. Buntkowsky, S. Derenne, O. Lafon, A. Huguet, F. Pourpoint,  ChemPhysChem, 2021, in press (https://doi.org/10.1002/cphc.202100334)

79) Bidentate Disilicate Framework for Bis-Grafted Surface Species
Y. Ishizaka, N. Arai, K. Matsumoto, H. Nagashima, K. Takeuchi, N. Fukaya, H. Yasuda, K. Sato, J.-C. Choi, Chem. Eur. J.(cover picture), 2021, 27,  12069–12077

78) Improved NMR transfer of magnetization from protons to half-integer spin quadrupolar nuclei at moderate and high magic-angle spinning      frequencies
J. S. Gómez, A. G. M. Rankin, J. Trébosc, F. Pourpoint, Y. Tsutsumi, H. Nagashima, O. Lafon, J.-P. Amoureux, Magnetic Resonance, 2021, 2(1) 447 – 464

77) Transparent Organogel Films Showing Extremely Efficient and Durable Anti-Icing Performance
C. Urata, H. Nagashima, B. D. Hatton, A. Hozumi, ACS Applied Materials & Interfaces, 2021, 13(24) 28925 – 28937

76) Efficient transfer of DNP‐enhanced 1H magnetization to half‐integer quadrupolar nuclei in solids at moderate spinning rate
H. Nagashima, J. Trébosc, Y. Kon, O. Lafon, J.‐P. Amoureux, Magnetic Resonance in Chemistry, 2021, early view (https://doi.org/10.1002/mrc.5121)

75) Pt-Catalyzed selective oxidation of alcohols to aldehydes with hydrogen peroxide using continuous flow reactors
Yoshihiro Kon, Takuya Nakashima, Akira Yada, Tadahiro Fujitani, Shun-ya Onozawa, Shu Kobayashi, and Kazuhiko Sato
Org. Biomol. Chem. 2021, 19, 1115-1121. (Synfacts, 2021, 17(04), 0476)

74) Ammonia Combustion Catalysts
Satoshi Hinokuma, Kazuhiko Sato
Chemistry Letters, Vol. 50 Commemorative Highlight Review, Vol. 50, pp. 752–759, 2021.

73) Effects of support materials and Ir loading on catalytic N2O decomposition properties
Satoshi Hinokuma, Takeshi Iwasa, Yoshihiro Kon, Tetsuya Taketsugu, Kazuhiko Sato
Catalysis Communications, 149, 106208, 2021.

72) Photocatalytic hydrogen evolution using a Ru (II)-bound heteroaromatic ligand as a reactive site
Takuya Sawaki, Tomoya Ishizuka, Nanase Namura, Dachao Hong, Mayuko Miyanishi, Yoshihito Shiota,
Hiroaki Kotani, Kazunari Yoshizawa, Jieun Jung, Shunichi Fukuzumi and Takahiko Kojima
Dalton Trans., 2020, 49, 17230-17242

71) N2O Decomposition Properties of Ru Catalysts Supported on Various Oxide Materials and SnO2
Satoshi Hinokuma, Takeshi Iwasa, Yoshihiro Kon, Tetsuya Taketsugu, Kazuhiko Sato
Scientific Reports, 10:21605, 2020.

70) Skewed electronic band structure induced by electric polarization in ferroelectric BaTiO3
Norihiro Oshime, Jun Kano, Eiji Ikenaga, Shintaro Yasui, Yosuke Hamasaki, Sou Yasuhara,
Satoshi Hinokuma, Naoshi Ikeda, Pierre‑Eymeric Janolin,Jean‑Michel Kiat, Mitsuru Itoh,
Takayoshi Yokoya, Tatsuo Fujii, Akira Yasui, Hitoshi Osawa
Scientific Reports, 10:10702, 2020.

69) Ammonia Combustion Properties of Copper Oxides-based Honeycomb and Granular Catalysts
Satoshi Hinokuma, Takeshi Iwasa, Kento Araki, Yusuke Kawabata, Shun Matsuki, Tetsuya Sato,
Yoshihiro Kon, Tetsuya Taketsugu, Kazuhiko Sato, Masato Machida
Journal of the Japan Petroleum Institute, Vol. 63, (5), pp. 274–281, 2020.

68) Mixed Proton–electron–oxide Ion Triple Conducting Manganite as Efficient Cobalt-free Cathode for Protonic Ceramic Fuel Cells
Ning Wang, Satoshi Hinokuma, Toshiaki Ina, Chunyu Zhu, Hiroki Habazaki, Yoshitaka Aoki
Journal of Materials Chemistry A, Vol. 8, pp. 11043–11055, 2020.

67) Cascade Reaction-Based Chemiresistive Array for Ethylene SensingShinsuke Ishihara, Ashish Bahuguna, Suneel Kumar, Venkata Krishnan, Jan Labuta, Takashi Nakanishi, Takeshi Tanaka, Hiromichi Kataura, Yoshihiro Kon, Dachao Hong
ACS Sens.2020, 5, 5, 1405–1410
https://pubs.acs.org/doi/abs/10.1021/acssensors.0c00194

66) A cobalt-substituted Keggin-type polyoxometalate for catalysis of oxidative aromatic cracking reactions in water
Yoshihiro Shimoyama, Satoru Tamura, Yasutaka Kitagawa, Dachao Hong, Yoshihiro Kon
Catal. Sci. Technol. 2020, in press

65) Selective Aerobic Oxidation of Allyl Phenyl Ether to Methyl Ketone by Palladium–Polyoxometalate Hybrid Catalysts
Satoru Tamura, Yoshihiro Shimoyama, Dachao Hong, and Yoshihiro Kon
Molecular Catalysis, 2020, 496, 111178.

64) Cooperative Effects of Hetero-Dinuclear IrIII-MII Complexes on Catalytic H2 Evolution from Formic Acid Dehydrogenation in Water
Dachao Hong, Yoshihiro Shimoyama, Yuji Ohgomori, Ryoichi Kanega, Hiroaki Kotani, Tomoya Ishizuka, Yoshihiro Kon, Yuichiro Himeda, Takahiko Kojima
(Cover picture) Inorg. Chem. 2020, 59, 17, 11976–11985

CY008018_IBC_PUBLICITY Our paper was adopted as a cover art of Inorganic Chemistry, 2020,  vol. 59, No.17.

63) Chemoselective Epoxidation of Allyloxybenzene by Hydrogen Peroxide Over MFI-Type Titanosilicate
Yoshihiro Kon, Takuya Nakashima, Dachao Hong, Xinyi Ji, Ryota Osuga, Satoru Ito, Tadahiro Fujitani, Kazuhiko Sato, and Toshiyuki Yokoi
Eur. J. Org. Chem. 2020, 2260-2263.
(Our paper was selected as a Hot Topic: Sustainable Chemistry of The Chemistry Europe.)

62) Observation of Low-γ Quadrupolar Nuclei by Surface-Enhanced NMR Spectroscopy
Hiroki Nagashima, Julien Trébosc, Yoshihiro Kon, Kazuhiko Sato, Olivier Lafon, and Jean-Paul Amoureux
J. Am. Chem. Soc. 2020, 142, 24, 10659–10672

61) Selective Observation of Chemical Structures at Surface and Core Regions of Heat-treated Poly(Acrylonitrile) Films by Solid-State NMR Spectroscopy

Jiayang Ma, Hiroki Nagashima, Shijun Wang, Xiaoran Roger Liu, You-lee Hong, Rongchun Zhang, and Toshikazu Miyoshi
Macromolecules 2019, 52, 21, 8384–8393

60) Probing Functionalities and Acidity of Calcined Phenylene-Bridged Periodic Mesoporous Organosilicates Using Dynamic Nuclear Polarization NMR, Diffuse Reflectance Infrared Fourier Transform Spectroscopy, and X-ray Photoelectron Spectroscopy

Cyril Pirez, Hiroki Nagashima, Franck Dumeignil, Olivier Lafon
J. Phys. Chem. C. 2020, 124, 11, 6110–6120

CY008018_IBC_PUBLICITY Our paper was adopted as a supplementary cover art of  Journal of Physical Chemistry C 2020,
Vol.124, No.11.

59) Efficient Photocatalytic CO2 Reduction by a Ni(II) Complex Having Pyridine Pendants through Capturing a Mg2+ Ion as a Lewis-Acid Cocatalyst
Dachao Hong, Takuya Kawanishi, Yuto Tsukakoshi, Hiroaki Kotani, Tomoya Ishizuka, Takahiko Kojima
J. Am. Chem. Soc. 2019, 141, 20309−20317

CY008018_IBC_PUBLICITY Our paper was adopted as a supplementary cover art of  Journal of American Chemical Society 2019,   Vol.141, No.51.

58) Plasmonic Ag@TiO2 Core–Shell Nanoparticles for Enhanced CO2 Photoconversion to CH4
Dachao Hong, Lian-Ming Lyu, Kenji Koga, Yoshihiro Shimoyama, Yoshihiro Kon
ACS Sustainable Chem. Eng. 2019, 7, 18955−18964

CY008018_IBC_PUBLICITY Our paper was adopted as a supplementary cover art of Inorganic Chemistry ACS Sustainable Chemistry & Engineering 2019, Vol.7, No.23.

57) Incorporation of Bulk Proton Carriers in Cubic Perovskite Manganite Driven by Interplays of Oxygen and Manganese Redox
Ning Wang, Satoshi Hinokuma, Toshiaki Ina, Hajime Toriumi, Misaki Katayama, Yasuhiro Inada, Chunyu Zhu, Hiroki Habazaki, and Yoshitaka Aoki,
Chem. Mater. 2019, 31, 8383−8393.

56) Mechanistic Insight into Synergistic Catalysis of Olefin Hydrogenation by a Hetero-Dinuclear RuII-CoII Complex with Adjacent Reaction Sites
Dachao Hong, Yuji Ohgomori, Yoshihiro Shimoyama, Hiroaki Kotani, Tomoya Ishizuka, Yoshihiro Kon, Takahiko Kojima,?Inorg. Chem. 2019, 58, 17, 11284-11288

CY008018_IBC_PUBLICITY The summary of our paper was adopted as an inside back cover of Inorganic Chemistry (Sep. 2019).

55) Titania-Catalyzed H2O2 Thermal Oxidation of Styrenes to Aldehydes
Ito, S., Kon, Y., Nakashima, T., Hong, D., Konno, H., Ino, D., Sato, K., Molecules 2019, 24, 2520.

54) Epoxide as precatalyst for metal-free catalytic transesterification
Tanaka, S., Nakashima, T., Satou, N., Oono H., Kon, Y., Tamura, M., Sato, K., Tetrahedron Lett. 2019, 60, 2009.

53) Dehydrative Allylation of Amine with Allyl Alcohol by Titanium Oxide Supported Molybdenum Oxide Catalyst,
Kon, Y., Nakashima, T., Fujitani, T., Murayama, T., Ueda, W., Synlett 2019, 30, 287-292. (SYNFACTS, 2019, 15(05), 0533.)

52) Atmospheric chemistry for gas-phase reaction of cyc-CF2CF2CF2CHXCHX-(X=H or F) with OH radicals in the temperature range of 253-328K

Guo, N. Zhang, T. Uchimaru, L. Chen, H-d. Quan, J. Mizukado, Atmospheric Environment 2019, 215, 116895.

51) Synthesis of hydrofluorocycloolefins through dehydrofluorination of hydrofluoroalkanes in amide solvents
W-n. Zhang, C-p. Zhang, Q. Guo, F-n. Lv, H-d. Quan, J. Fluorine Chem. 2019, 226, 109342.

50) A novel vapor-phase synthetic route for fluorometaane toward highly efficient industrial production
Yang, C-p. Zhang, H-e. Yang, H-d. Quan, Chemistry Select 2019, 4, 527-530.

49) Atmospheric chemistry of perfluoronitriles: Environmental impact and experimental evidence related to N2O and NO formation
Guo, L. Chen, S. Kutsuna, H-d. Quan, J. Mizukado, Atmospheric Environment 2019, 198, 175-182.

48) Versatile etherification of alcohols with allyl alcohol by a titanium oxide-supported molybdenum oxide catalyst: gradual generation from titanium oxide and molybdenum oxide
Kon, Y., Fujitani, T., Nakashima, T., Murayama, T., Ueda, W., Catal. Sci. Technol. 2018, 8, 4618.

CY008018_IBC_PUBLICITY The summary of our paper was adopted as an inside back cover of Catalysis Science & Technology (Aug. 2018).

47) Synthesis of 1H-polychlorofluorocycloolefins
Yang, C-p. Zhang, H-e. Yang, H-d. Quan, J. Fluorine Chem. 2018, 216, 96-101.

46) Deactivation of porous aluminum fluoride-supported nobel metallic catalysts used in the hydrodechlorination of 1-chlorohepatafluorocylopentene
F-y. Qing, C-p. Zhang, H-d. Quan, Greenhouse Gases: Science and Technology 2018, 8, 854-862.

45) Atmospheric chemistry of E-CF3CH=CHCF3: Reaction kinetics of OH radicals and products of OH-initiated oxidation
F-y. Qing, Q. Guo, N. Zhang, L, Chen , H-d. Quan, J. Mizukado, Chemical Physics Letter 2018, 706, 93-98.

44) Synthesis of hydrofluorocyclopentanes by vapor-phase catalytic hydrodehalogenation
F-y. Qing, C-p. Zhang, H-d. Quan, J. Fluorine Chem. 2018, 213, 61-67.

43) Kinetics, products, and mechanism for reaction of E-CF3CH=CHC2F5 with OH radicals in gas phase and atmospheric implications
Guo, N. Zhang, T. Uchimaru, L. Chen, H-d. Quan, J. Mizukado, Atmospheric Environment 2018, 185, 7-14.

42) Isomerization of hydrofluorocyclopentenes promoted by fluoride anion
C-p. Zhang, Ni Zhang, X-q. Jia, N. Li, H-d. Quan, Green and Sustainable Chemistry 2018, 8, 115-129.

41) Atmospheric chemistry of cyc-CF2CF2CF2CH=CH-: Kinetics, products, and mechanism of gas-phase reaction with OH radicals, and atmospheric implications
Guo, N. Zhang, T. Uchimaru, L. Chen, H-d. Quan, J. Mizukado, Atmospheric Environment 2018, 179, 69-76.

40) Mechanistic Insights into Homogeneous Electrocatalytic and Photocatalytic Hydrogen Evolution Catalyzed by High-Spin Ni(II) Complexes with S2N2-Type Tetradentate Ligands
Dachao Hong, Yuto Tsukakoshi, Hiroaki Kotani, Tomoya Ishizuka, Kei Ohkubo, Yoshihito Shiota, Kazunari Yoshizawa, Shunichi Fukuzumi, Takahiko Kojima
Inorg. Chem. 2018, 57, 12, 7180-7190

39) Observation of proximities between spin-1/2 and quadrupolar nuclei in solids: Improved robustness to chemical shielding using adiabatic symmetry-based recoupling.
Nagashima, A. S. Lilly Thankamony, J. Trebosc, L. Montagne, G. Kerven, J.-P. Amoureux, O. Lafon,
Solid State Nuclear Magnetic Resonance 2018, 94, 7-19

38) Quaternary Alkyl Ammonium Salt-Catalyzed Transformation of Glycidol to Glycidyl Esters by Transesterification of Methyl Esters
S. Tanaka, T. Nakashima, T. Maeda, M. Ratanasak, J. Hasegawa, Y. Kon, M. Tamura, K. Sato, ACS catal. 2018, 8, 1097-1103.

37) W-Ti-O Mixed Metal Oxide Catalyzed Dehydrative Cross-etherification of Alcohols
A.Yada, T. Murayama, J. Hirata, T. Nakashima, M. Tamura, Y. Kon, W. Ueda, Chem. Lett. 2018, 47, 447-449.

36) Machine Learning Approach for Prediction of Reaction Yield with Simulated Catalyst Parameters
A. Yada, K. Nagata, Y. Ando, T. Matsumura, S. Ichinoseki, K. Sato, Chem. Lett. 2018, 47, 284-287.

35) Palladium‐Catalyzed Dehydrogenative Coupling Reaction of Terminal Alkynes with Unactivated Alkenes
A. Yada, S. Nishi, Y. Sato, S. Ichinoseki, M. Murakami, J. Chin. Chem. Soc. 2018, 65, 117-121.

34) Visible-Light-Driven Photocatalytic CO2 Reduction by a Ni(II) Complex Bearing a Bioinspired Tetradentate Ligand for Selective CO Production
Dachao Hong, Yuto Tsukakoshi, Hiroaki Kotani, Tomoya Ishizuka, Takahiko Kojima
J. Am. Chem. Soc. 2017, 139, 19, 6538-6541

33) Seed-Assisted Synthesis of MWW-Type Zeolite with Organic Structure-Directing Agent-Free Na-Aluminosilicate Gel System
Y. Kamimura, K. Itabashi, Y. Kon, A. Endo, T. Okubo, Chem. Asian J. 2017, 12, 530-542.

32) Buttressing Salicylaldehydes: A Multipurpose Directing Group for C(sp3)??-H Bond Activation
A. Yada, W. Liao, Y. Sato, M. Murakami, Angew. Chem. Int. Ed. 2017, 56, 1073-1076.

31) Metal-catalyzed hydrogen peroxide oxidation for synthesis of value-added chemicals
Y. Kon, J. Jpn. Petrol. Inst. 2017, 60, 159-169.

30) Copper-Catalyzed Selective Oxygenation of Methyl and Benzyl Substituents in Pyridine with O2
T. Abe, S. Tanaka, A. Ogawa, M. Tamura, K. Sato, S. Itoh, Chem. Lett. Accepted.

29) Direct Conversion of Glycerol to Allyl Alcohol Over Alumina-Supported Rhenium Oxide
Y. Kon, M. Araque, T. Nakashima, S. Paul, F. Dumeignil, B. Katryniok, ChemistrySelect 2017, 2, 9864-9868.

28) Synthesis of Z-1,1,1,4,4,4-hexafluoro-2-butenen from hexachlorobutadiene
Chengping Zhang, Xiaoqing Jia, Heng-dao Quan, J. Fluorine Chem. 191,77-83(2016).

27) Investigation on Cl-F exchange mechanism occurring at C(sp2) and C (sp3) orbitals of halogenated cyclopentene
Chengping Zhang, Feiyao Qing, Heng-dao Quan, Akira Sekiya, J. Fluorine Chem. 191 , 84-89(2016).

26) Mixed-picolinate and -Quinaldinate Iron(III) Complexes for Catalytic Oxidation of Alcohols with Hydrogen Peroxide
S. Tanaka, Y. Kon, A. Ogawa, Y. Uesaka, M. Tamura, K. Sato, ChemCatChem,? 2016, 8, 2930-2938.

25) Cerium Complex-Catalyzed Oxidation of Arylmethanols under Atmospheric Pressure of Dioxygen and Its Mechanism through a Side-On m-Peroxo Dicerium(IV) Complex
M. Paul, S. Shirase, Y. Morimoto, L. Mathey, M. Balasubramanian, S. Tanaka, S. Ito, H. Tsurugi, K. Mashima, Chem. Eur. J., 22, 4008-4014 (2016). (Front Cover)

24) Iron-catalyzed Selective Oxidation of α,β-Unsaturated Aldehydes to α,β-Unsaturated Carboxylic Acids by Molecular Oxygen
S. Tanaka, Y. Kon, Y. Uesaka, R. Morioka, M. Tamura, K. Sato, Chem. Lett., 45, 188-190 (2016). (Editor’s Choice)

23) Isomerization of Halogenated Cyclopentene over a NH4F Catalyst
H-d. Quan, C-p. Zhang, R-z. Hu, F-y. Qing, ChemCatChem., 8, 1474-1478(2016).

22) Synthesis of 2,3,3,3-tetrafluoropropene via vapor-phase catalytic fluorination in presence of Cr-based catalys,
R-z. Hu, C-p. Zhang, D-p. Liu, H-d,Quan, J. Fluorine Chem., 185, 187-190(2016).

21) Therotical and experimental studies for preparing 1,1-dibromo-1,2,2,2-tetrafluoroethane on gas-phase bromination of 1,1,1,2-tetrafluoroethane,
R-z. Hu, C-p. Zhang, F-y. Qing, H-d. Quan, J. Fluorine Chem. 185, 91-95(2016).

20) Salt-Free Reduction of Nonprecious Transition-Metal Compounds : Generation of Amorphous Ni Nanoparticles for Catalytic C-C Bond Formation
T. Yurino, Y. Ueda, Y. Shimizu, S. Tanaka, H. Nishiyama, H. Tsurugi, K. Sato, K. Mashima, Angew. Chem. Int. Ed., 54, 14437-14441 (2015).

19) Kinetics of gas-phase reactions of cyc-CF2CF2CF2CHFCH2andtrans-cyc-CF2CF2CF2CHFCHF with OH radicals between 253 and328 K
N. Zhang, L. Chen, T. Uchimaru, F-y. Qing, J. Mizukado, H-d. Quan, H. Suda, Chemical Physics Letter, 639, 199-204(2015).

18) Synthesis of 1,1,2,2,3,3,4-heptafluorocyclopentane as a new generation of green solvent
C-p. Zhang, F-y. Qing, H-d.,Quan, A. Sekiya, J. Fluorine Chem., 181, 11-16(2015).

17) Study on the synthesis of toluene-2.4-diisocyanate via amine and carbonyl fluoride
N. Zhang, H-d. Quan, X-m. Zhou, A. Sekiya, J. Fluorine Chem. 178, 208-213(2015).

16) Syntheses of isocyanates via amines and carbonyl fluoride
Heng-dao Quan, Ni Zhang, Xiaomeng Zhou, Hua Qian, Akira Sekiya, J. Fluorine Chem. 176, 26-30(2015).

15) Rate constants for the gas-phase reactions of (Z)-CF3CH=CHF and ?-CF3CH=CHF with OH radicals at 253-328K
N. Zhang, L. Chen, J. Mizukado, H-d. Quan, H. Suda, Chemical Physical Letters 621, 78-84(2015).

14) Telomerization of vinylchloride with chloroform initiated by ferrous chloride-dimethylacetamide under ultrasonic conditions
H. Qian, H-d. Quan, Advances in chemistry, Volume 2015, Article ID 637653, 4 Pages (2015).

13) Chemoselective Hydrogen Peroxide Oxidation of Allylic and Benzylic Alcohols under Mild Reaction Conditions Catalyzed by Simple Iron-picolinate Complexes
S. Tanaka, Y. Kon, T. Nakashima, K. Sato, RSC Adv., 4, 37674-37678 (2014).

12) Selective Hydrogen Peroxide Oxidation of Sulfide to Sulfoxides or Sulfones with MWW-type Titanosilicate Zeolite Catalyst under Organic Solvent-free Conditions
Y. Kon, T. Yokoi, M. Yoshioka, S. Tanaka, Y. Uesaka, T. Mochizuki, K. Sato, T. Tatsumi, Tetrahedron, 70, 7584-7592 (2014).

11) Chemoselective Palladium-Catalyzed Oxidation of Vinyl Ether to Acetate Using Hydrogen Peroxide
Y. Kon, S. Tanaka, T. Nakashima, K. Sato, H. Shimada, J. Chin. Chem. Soc. (Special Issue for Green & Sustainable Chemistry), 61, 749-756 (2014).

10) Practical Iron-Catalyzed Hydrogen Peroxide Epoxidation of Aromatic Olefins using as Combination of Two Kinds of Simple Picolinate Ligands under Halide-Free Reaction Conditions
T. Chishiro, Y. Kon, T. Nakashima, M. Goto, K. Sato, Adv. Synth. Catal., 356, 623-627 (2014).

9) Selective oxidation of bulky sulfides to sulfoxides over titanosilicates having an MWW structure in the presence of H2O2 under organicsolvent-free conditions
Y. Kon, T. Yokoi, M. Yoshioka, Y. Uesaka, H. Kujira, K. Sato, T. Tatsumi, Tetrahedron Lett., 54, 4918-4921 (2013).

8) Pt-Catalyzed Oxidative Rearrangement of Cyclic Tertiary Allylic Alcohol to Enones Using Aqueous Hydrogen Peroxide
T. Nagamine, Y. Kon, K. Sato, Chem. Lett., 41, 744-746 (2012).

7) Development of Oxidation Systems Using Hydrogen Peroxide for Synthesis of Fine Chemicals
Y. Kon, T. Chishiro, H. Uchida, K. Sato, H. Shimada, Journal of the Japan Petroleum Institute, 55, 277-286 (2012).

6) Unique Salt Effect on Highly Selective Syntheses of Acid-Labile Terpene and Styrene Oxides with Tungsten-H2O2 Catalytic System under Acidic Aqueous Conditions
H. Hachiya, Y. Kon, Y. Ono, K. Takumi, N. Sasagawa, Y. Ezaki, K. Sato, Synthesis, 44, 1672-1678 (2012).

5) Synthesis of microporous fluorinated chromia with a sharp pore distribution.
X-q. Jia, H-d. Quan, M. Tamura, A. Sekiya, RSC Adv., 2012, 2(16), 6695-6700(2012).

4) Unique Salt Effect on the High Yield Synthesis of Acid-Labile Terpene Oxides Using Hydrogen Peroxide under Acidic Aqueous Conditions
H. Hachiya, Y. Kon, Y. Ono, K. Takumi, N. Sasagawa, Y. Ezaki, K. Sato, Synlett, 2819-2822 (2011).

3) An Effective Synthesis of Acid-Sensitive Epoxides via Oxidation of Terpenes and Styrenes using Hydrogen Peroxide under Organic Solvent-free Conditions
Y. Kon, H. Hachiya, Y. Ono, T. Matsumoto, K. Sato, Synthesis, 1092-1098 (2011).

2) Palladium-catalyzed oxidation of vinyl ether to acetate with hydrogen peroxide
Y. Kon, T. Chishiro, D. Imao, T. Nakashima, T. Nagamine, H. Hachiya, K. Sato, Tetrahedron Lett., 52, 6739-6742 (2011).

1) Preparation of cis-1,1,1,4,4,4-hexafluorobut-2-ene by cis-selective semi-hydrogenation of perfluoro-2-butyne
X-q. Jia, X-m. Zhou, H-d. Quan, M.Tamura, A.Sekiya, J. Fluorine Chem., 132, 1188-1193 (2011).

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