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Hydrogen Storage and Release via Carbon Dioxide Hydrogenation to Formate Salts under High-Pressure Conditions with Ir Complex and Subsequent Formic Acid Dehydrogenation

Seo Ono, Ryoichi Kanega, Hajime Kawanami* ChemistryOpen 2025, 14, e202500032

One-Step Esterification of Phosphoric, Phosphonic and Phosphinic Acids with Organosilicates: Phosphorus Chemical Recycling of Sewage Waste

Yuki Naganawa, Kei Sakamoto, Akira Fujita, Kazuya Morimoto, Manussada Ratanasak, Jun-ya Hasegawa, Masaru Yoshida, Kazuhiko Sato, Yumiko Nakajima 　Angew. Chem. Int. Ed. 2025, 64, e202416487.

Continuous-flow synthesis of carboxylic acids from alcohols via platinum and silicon dioxide-catalyzed hydrogen peroxide oxidation

Yoshihiro Kon,* Takuya Nakashima, Yoshiki Makino, Shun-ya Onozawa, Hiroyuki Miyamura, Shū Kobayashi,* Kazuhiko Sato* Org. Biomol. Chem., 2025,23, 2125-2132

Iridium complexes supported on cross-linked polyacrylic acid as release-and-catch catalysts for continuous formic acid dehydrogenation

Keito Sawahara, Shinji Tanaka, Ryota Gemma, Ryoichi Kanega, Hajime Kawanami * Catal. Sci. Technol., 2025,15, 52-61

Direct Formic Acid Production by CO2 Hydrogenation with Ir Complexes in HFIP under Supercritical Conditions

Seo Ono, Ryoichi Kanega, Hajime Kawanami* Organometallics, 43 (19), 2024, 2213-2220

Continuous-inline extraction of polar co-solvent during sequential flow reactions

Kwihwan Kobayashi*, Jun Matsuzawa, Hajime Kawanami and Nagatoshi Koumura* Reaction Chemistry & Engineering, 2024, 9, 3116 - 3121.

Selective Hydrogenation of Quinizarins to Leuco-quinizarins and Their Direct Derivatization Using Flow-Batch-Separator Unified Reactors under Continuous-Flow Conditions.

Hiroyuki Miyamura*; Aditya Sharma; Masakazu Takata; Ryosuke Kajiyama; Shū Kobayashi; Yoshihiro Kon ACS Catalysis 2024, 14, 10317-10323.

Cd2+-Specific Fluorescence Response of Methoxy-Substituted N,N‐Bis(2-quinolylmethyl)-2-methoxyaniline Derivatives

Yuji Mikata, Nao Tosaka, Saori Yasuda, Yui Sakurai, Sunao Shoji, Hideo Konno, Takashi Matsuo Inorg. Chem. 2024, 63, 18, 8026-8037.

Probing the Surface of Oxide Nanoparticles Using DNP-Enhanced High-Resolution NMR of Quadrupolar Nuclei

Hiroki Nagashima*, Farahnaz Maleki, Julien Trébosc, Rajesh Belgamwar, Vivek Polshettiwar, Myrtil Kahn, Yoshihiro Kon, Gianfranco Pacchioni, Olivier Lafon*, and Jean-Paul Amoureux* J. Phys. Chem. Lett. 2024, 15, 18, 4858–4863

Iridium Catalyst Immobilized on Crosslinked Polyethyleneimine for Continuous Hydrogen Production Using Formic Acid

Keito Sawahara, Dr. Shinji Tanaka, Dr. Tetsuya Kodaira, Dr. Ryoichi Kanega, Dr. Hajime Kawanami* ChemSusChem, Vol.17 (1), 2024, e202301282

Continuous Synthesis of Epoxides from Alkenes by Hydrogen Peroxide with Titanium Silicalite-1 Catalyst Using Flow Reactors

Yoshihiro Kon,* Takuya Nakashima, Yoshiki Makino, Hiroki Nagashima, Shun-ya Onozawa, Shū Kobayashi,* Kazuhiko Sato* Adv. Synth. Catal. 2023, 365, 3227–3233

Synthesis of Multiblock Copolymer Composed of Biodegradable Poly(butylene succinate) and Poly(2-pyrrolidone): Impact of Each Block Length on the Mechanical Properties

Hideaki Ono, Yasutaka Kawai, Seisuke Ata, Hiroyuki Minamikawa, Kazuma Kurihara, Shinji Tanaka, Masaru Yoshida Macromol. Rapid Commun. August 2023,2370036

One-Pot Synthesis of Polymers Containing P-C Bonds in the Main Chain

Siby Mathew, Yuki Naganawa, Fan Jiang, Raphael Wischert, Stephane Streiff, Pascal Metivier, Yumiko Nakajima* Macromol. Rapid Commun. 2023, 44, 2200921　

Effect of methoxy substituents on fluorescent Zn2+/Cd2+ selectivity of bisquinoline derivatives with a N,N′-dimethylalkanediamine skeleton

Yuji Mikata, * Marin Tanaka, Saori Yasuda, Aya Tsuruta　 Taeka Hagiwara, Hideo Konno and Takashi Matsuo Dalton Trans., 2023,52, 7411-7420

Direct Conversion of Low-Concentration CO2 into N-Aryl and N-Alkyl Carbamic Acid Esters Using Tetramethyl Orthosilicate with Amidines as a CO2 Capture Agent and a Catalyst

Hiroki Koizumi, Katsuhiko Takeuchi*,Kazuhiro Matsumoto, Norihisa Fukaya, Kazuhiko Sato, Masahito Uchida, Seiji Matsumoto, Satoshi Hamura, Junya Hirota, Makoto Nakashige, and Jun-Chul Choi* J. Org. Chem. 2023, 88, 8, 5015–5024

Borane-Protecting Strategy for Hydrosilylation of Phosphorus-Containing Olefins

Yuki Naganawa*, Akira Fujita, Kei Sakamoto, Shinji Tanaka, Kazuhiko Sato, and Yumiko Nakajima* ACS Omega 2023, 8, 6, 5672–5682

Synthesis of Glycerol Carbonate from Glycerol and CO2 Using CaO as a Dehydrating Agent

Katsuhiko Takeuchi, Kazuhiro Matsumoto, Norihisa Fukaya, Kohtaro Osakada, Kazuhiko Sato, Jun-Chul Choi* sian Journal of Organic Chemistry, 2022, 11, e202200212.

Cd2+-selective fluorescence response of TQEN (N,N,N′,N′-tetrakis(2-quinolylmethyl)ethylenediamine) derivatives bearing ether oxygen-binding sites

Yuji Mikata, * Minori Kaneda, Sh izuka Yonemura, Miyu Akedo, Hideo Konno and Takashi Matsuo Dalton Trans., 2022,51, 17170-17179

Synthesis of organic carbamates as polyurethane raw materials from CO2: the quest for metal alkoxides as regenerable reagents

Katsuhiko Takeuchi, Kazuhiro Matsumoto, Norihisa Fukaya, Kazuhiko Sato, Jun-Chul Choi* Dalton Transactions, 2022, 51, 15631-15643.

In situ formic acid dehydrogenation observation using a UV-vis-diffuse-reflectance spectroscopy system

Risheng Li, Tetsuya Kodaira*, and Hajime Kawanami* Chemical Communications, 2022, 58 (79), 11021-11172

Asymmetric Dehydrative Cyclization of Allyl Alcohol to Cyclic Ether Using Chiral Brønsted Acid/CpRu(II) Hybrid Catalysts: A DFT Study of the Origin of Enantioselectivity

Manussada Ratanasak, Shinji Tanaka, Masato Kitamura*, and Jun-ya Hasegawa* J. Org. Chem. 2022, 87, 19, 13062–13072

Laser Ablation Nanoarchitectonics of Au–Cu Alloys Deposited on TiO2 Photocatalyst Films for Switchable Hydrogen Evolution from Formic Acid Dehydrogenation

Dachao Hong*, Aditya Sharma, Dianping Jiang, Elena Stellino, Tomohiro Ishiyama, Paolo Postorino, Ernesto Placidi, Yoshihiro Kon, and Kenji Koga* ACS Omega2022, 7, 35, 31260–31270

Heterolytic cleavage of a Si–H bond by a metal–ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes

Kosuke Iizuka, Yumiko Nakajima * and Kazuhiko Sato Dalton Trans., 2022,51, 12781-12785

Production of lactic acid mediated by compressed carbon dioxide on heterogeneous Ni(ii) catalysts: a facile approach

Maya Chatterjee, * Abhijit Chatterjee and Hajime Kawanami * Green Chem., 2022,24, 6145-6155

DNP NMR spectroscopy enabled direct characterization of polystyrene-supported catalyst species for synthesis of glycidyl esters by transesterification

Shinji Tanaka, * Yumiko Nakajima, Atsuko Ogawa, Takashi Kuragano, Yoshihiro Kon, Masanori Tamura, Kazuhiko Sato and Christophe Copéret * Chem. Sci., 2022,13, 4490-4497

Selectivity controlled transformation of carbon dioxide into a versatile bi-functional multi-carbon oxygenate using a physically mixed ruthenium–iridium catalyst

Maya Chatterjee, * Abhijit Chatterjee, Mitsunori Kitta and Hajime Kawanami * Catal. Sci. Technol., 2021,11, 4719-4731

Aerobic oxygenation of α-methylene ketones under visible-light catalysed by a CeNi3 complex with a macrocyclic tris(salen)-ligand

Haruki Nagae, Kazutaka Sakamoto, Sakiko Fujiwara, Tobias Schindler, Yoshihiro Kon, Kazuhiko Sato, * Jun Okuda * and Kazushi Mashima * Chem. Commun., 2021,57, 11169-11172

N-Aryl and N-Alkyl Carbamates from 1 Atmosphere of CO2

Katsuhiko Takeuchi, Ming-Yu Chen, Hao-Yu Yuan, Hiroki Koizumi, Kazuhiro Matsumoto, Norihisa Fukaya, Yoong-Kee Choe, Shinji Shigeyasu, Seiji Matsumoto, Satoshi Hamura, Jun-Chul Choi* Chem. Eur. J. 2021, 27, 18066-18073.

RuO2 Nanoparticle-Embedded Graphitic Carbon Nitride for Efficient Photocatalytic H2 Evolution

Yoshihiro Shimoyama, Kenji Koga, Hiroyasu Tabe, Yusuke Yamada, Yoshihiro Kon, Dachao Hong* ACS Appl. Nano Mater. 2021, 4, 11, 11700–11708

Hydroxycarbonylation of alkenes with formic acid using a rhodium iodide complex and alkyl ammonium iodide

Masaki Okada, Katsuhiko Takeuchi, Kazuhiro Matsumoto, Tomoharu Oku, Jun-Chul Choi* Org. Biomol. Chem. 2021, 19, 8727-8734

Bidentate Disilicate Framework for Bis-Grafted Surface Species (Chem. Eur. J. 47/2021)

Yusuke Ishizaka,Natsumi Arai,Dr. Kazuhiro Matsumoto,Dr. Hiroki Nagashima,Dr. Katsuhiko Takeuchi,Dr. Norihisa Fukaya,Dr. Hiroyuki Yasuda,Dr. Kazuhiko Sato,Dr. Jun-Chul Choi Chem. Eur. J. 2021, 27, 12069-12077.

Hydrogen peroxide production from oxygen and formic acid by homogeneous Ir–Ni catalyst

Yoshihiro Shimoyama, Yuji Ohgomori, Yoshihiro Kon and Dachao Hong* Dalton Trans., 2021, 50, 9410-9416

Ammonia Combustion Catalysts

Satoshi Hinokuma * and Kazuhiko Sato Chem. Lett. 2021, 50, 752–759

Metal–ligand cooperation behaviour of Fe and Co complexes bearing a tetradentate phenanthroline-based PNNP ligand

Yumiko Nakajima*, Tomohiro Takeshita and Nai-Yuan Jheng Dalton Trans., 2021,50, 7532-7536

Direct Amidation of Esters and Amines under Continuous‐Flow Method

Md. Nurnobi Rashed, Koichiro Masuda, Tomohiro Ichitsuka, Nagatoshi Koumura*, Kazuhiko Sato*, Shū Kobayashi* Adv. Synth. Catal. 2021, 363, XXXX–XXXX; DOI: 10.1002/adsc.202001496).

Formate-driven catalysis and mechanism of an iridium–copper complex for selective aerobic oxidation of aromatic olefins in water

Yoshihiro Shimoyama, Yasutaka Kitagawa, Yuji Ohgomori, Yoshihiro Kon and Dachao Hong * Chem. Sci., 2021,12, 5796-5803

Treating octasilanol [Si8O12][OH]8 with tetramethoxysilane and trimethoxyvinylsilane: a halogen-free synthetic route to alkoxysilyl-substituted double-four-ring siloxanes

Takeshi Nozawa, Toshiaki Kobayashi, Tomohiro Matsumoto, Fujio Yagihashi, Kazuhiko Sato, and Masayasu Igarashi* Dalton Trans., 2021,50, 1594-1598

Organocatalytic ring-opening polymerization of cyclotrisiloxanes using silanols as initiators for the precise synthesis of asymmetric linear polysiloxanes

Keita Fuchise*, Toshiaki Kobayashi, Kazuhiko Sato*, and Masayasu Igarashi* Polym. Chem., 2020,11, 7625-7636

Synthesis and Structure of Multinuclear Pd(II) Complexes Bridged by Phosphide or Azide Ligands

Katsuhiko Takeuchi, Kun-Woo Kim, Yong-Joo Kim*, Norihisa Fukaya, Kazuhiko Sato, and Jun-Chul Choi* ACS Omega 2020, 5, 46, 29706–29713

Cooperative Effects of Heterodinuclear IrIII–MII Complexes on Catalytic H2 Evolution from Formic Acid Dehydrogenation in Water

Dachao Hong*, Yoshihiro Shimoyama, Yuji Ohgomori, Ryoichi Kanega, Hiroaki Kotani, Tomoya Ishizuka, Yoshihiro Kon, Yuichiro Himeda, and Takahiko Kojima Inorg. Chem. 2020, 59, 17, 11976–11985

Probing Functionalities and Acidity of Calcined Phenylene-Bridged Periodic Mesoporous Organosilicates Using Dynamic Nuclear Polarization NMR, Diffuse Reflectance Infrared Fourier Transform Spectroscopy, and X-ray Photoelectron Spectroscopy

Cyril Pirez*, Hiroki Nagashima, Franck Dumeignil, and Olivier Lafon* J. Phys. Chem. C 2020, 124, 11, 6110-6120

Switching of Fluorescent Zn/Cd Selectivity in N,N,N′,N′-Tetrakis(6-methoxy-2-quinolylmethyl)-1,2-diphenylethylenediamine by One Asymmetric Carbon Atom Inversion

Yuji Mikata* , Kana Nozaki ,Marin Tanaka , Hideo Konno , Arimasa Matsumoto , Masaya Kawamura, and Shin-ichiro Sato Inorg. Chem. 2020, 59, 8, 5313–5324

DNP NMR spectroscopy of cross-linked organic polymers: rational guidelines towards optimal sample preparation

Shinji Tanaka*, Wei-Chih Liao, Atsuko Ogawa, Kazuhiko Sato and Christophe Copéret* Phys. Chem. Chem. Phys., 2020, 22, 3184-3190

Efficient Photocatalytic CO2 Reduction by a Ni(II) Complex Having Pyridine Pendants through Capturing a Mg2+ Ion as a Lewis-Acid Cocatalyst

Dachao Hong，Takuya Kawanishi，Yuto Tsukakoshi，Hiroaki Kotani，Tomoya Ishizuka，Takahiko Kojima* J. Am. Chem. Soc., 2019, 141, 20309-20317

Plasmonic Ag@TiO2 Core–Shell Nanoparticles for Enhanced CO2 Photoconversion to CH

Dachao Hong*, Lian-Ming Lyu, Kenji Koga, Yoshihiro Shimoyama, Yoshihiro Kon* ACS Sustainable Chem. Eng., 2019, 7, 18955-18964

Nickel‐Catalyzed Selective Cross‐Coupling of Chlorosilanes with Organoaluminum Reagents

Yuki Naganawa*, Haiqing Guo, Kei Sakamoto, Yumiko Nakajima* ChemCatChem, 2019, 11, 3756-3759

Mechanistic Insight into Synergistic Catalysis of Olefin Hydrogenation by a Hetero-Dinuclear RuII–CoII Complex with Adjacent Reaction Sites

Dachao Hong*, Yuji Ohgomori, Yoshihiro Shimoyama,Hiroaki Kotani, Tomoya Ishizuka, Yoshihiro Kon,Takahiko Kojima* Inorg. Chem., 2019, 58, 11284-11288

Synthesis of hydrosilanes via Lewis-base-catalysed reduction of alkoxy silanes with NaBH4

Keiya Aoyagi, Yu Ohmori, Koya Inomata, Kazuhiro Matsumoto, Shigeru Shimada, Kazuhiko Sato and Yumiko Nakajima* Chem. Commun., 2019, 55, 5859-5862

Direct Installation of a Silyl Linker on Ready-Made NHC Ligands: Immobilized NHC-Pd Complex for Buchwald–Hartwig Amination

Tomoteru Mizusaki，Kazuhiro Matsumoto，Katsuhiko Takeuchi，Norihisa Fukaya，Yukio Takagi，Jun-Chul Choi* Organometallics, 2019, 38, 1872-1876

Heterogeneous hydrosilylation reaction catalysed by platinum complexes immobilized on bipyridine-periodic mesoporous organosilicas

Yuki Naganawa, Yoshifumi Maegawa, Haiqing Guo, Sandeep Suryabhan Gholap, Shinji Tanaka, Kazuhiko Sato, Shinji Inagaki* and Yumiko Nakajima* Dalton Trans., 2019, 48, 5534-5540

[Pd(4-R3Si-IPr)(allyl)Cl], a Family of Silyl-Substituted Pd–NHC Complexes: Catalytic Systems for the Buchwald–Hartwig Amination

Norihisa Fukaya*, Tomoteru Mizusaki, Kouhei Hatakeyama, Yuto Seo, Yuuya Inaba, Kazuhiro Matsumoto, Vladimir Ya. Lee, Yukio Takagi, Junpei Kuwabara, Takaki Kanbara, Yoong-Kee Choe, Jun-Chul Choi* Organometallics, 2019, 38, 375-384

Methoxy-substituted tetrakisquinoline analogs of EGTA and BAPTA for fluorescence detection of Cd2+

Yuji Mikata, * Minori Kaneda, Hideo Konno, Arimasa Matsumoto, Shin-ichiro Sato, Masaya Kawamura and Satoshi Iwatsuki Dalton Trans., 2019,48, 3840-3852

Silica Support‐Enhanced Pd‐Catalyzed Allylation Using Allylic Alcohols

Ken Motokura,* Marika Ikeda, Minjune im, Kiyotaka Nakajima, Sae Kawashima, Masayuki ambo, Wang‐Jae Chun, Shinji Tanaka ChemCatChem 2018, 10, 4536–4544

Sequence‐Controlled Catalytic One‐Pot Synthesis of Siloxane Oligomers

Kazuhiro Matsumoto, Shigeru Shimada, Kazuhiko Sato Chem. Eur.J.2019, 25,920 –928

Versatile etherification of alcohols with allyl alcohol by a titanium oxide-supported molybdenum oxide catalyst: gradual generation from titanium oxide and molybdenum oxide

Yoshihiro Kon*, Tadahiro Fujitani, Takuya Nakashima, Toru Murayama　and Wataru Ueda* Catal. Sci. Technol., 2018, 8, 4618-4625

Organocatalytic controlled/living ring-opening polymerization of cyclotrisiloxanes initiated by water with strong organic base catalysts

Keita Fuchise*, Masayasu Igarashi, Kazuhiko Sato*, and Shigeru Shimada * Chem. Sci., 2018,9, 2879-2891

Replacement of quinolines with isoquinolines affords target metal ion switching from Zn2+ to Cd2+ in the fluorescent sensor TQLN (N,N,N′,N′-tetrakis(2-quinolylmethyl)-2,6-bis(aminomethyl)pyridine)

Yuji Mikata,* Ayaka Takekoshi, Minori Kaneda, Hideo Konno, Keiko Yasuda, Masato Aoyama and Satoshi Tamotsu Dalton Trans., 2017,46, 632-637

Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(ii) and its derivatives

Go Nakamura, Yumiko Nakajima*, Kazuhiro Matsumoto, Venu Srinivas and Shigeru Shimada* Catal. Sci. Technol., 2017, 7, 3196-3199

By‐Product‐Free Siloxane‐Bond Formation and Programmed One‐Pot Oligosiloxane Synthesis

Kazuhiro Matsumoto, Kappam Veettil Sajna, Yasushi Satoh，Kazuhiko Sato, Shigeru Shimada* Angew. Chem., Int. Ed., 2017, 56, 3168-3171

書籍

触媒化学融合研究センター職員が、執筆に関わった化学系書籍を紹介します。

有機合成のためのフロー化学

著者：F. Darvas 編、G. Dormán 編、V. Hessel 編
小林　修監訳・編著、小野澤　俊也監訳・編著
出版年月日：2020/03/23
ISBN：9784807909926
判型・ページ数：A5・288ページ

酸化還元反応

著者日本化学会編・佐藤一彦・北村雅人著
シリーズ名：化学の要点シリーズ【1】巻
初版出版年月日：2012/1/30
ISBN：978-4-320-04406-7
判型・ページ数：B6・176ページ

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横浜ゴム株式会社	産業技術総合研究所
日本エアリキード	相模中央化学研究所
三井化学株式会社	愛媛大学
雪印メグミルク株式会社	神戸大学
シャープ株式会社（2名）	筑波大学
東京応化工業株式会社（2名）	横浜国立大学
TOTO株式会社	東北大学
住友精化株式会社	和歌山県工業技術センター
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