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研究チームの成果については産総研公式HP:研究成果をご覧ください。

 

【発表論文:カバーピクチャー】  

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【2020】

 

Cooperative Effects of Heterodinuclear IrIII–MII Complexes on Catalytic H2 Evolution from Formic Acid Dehydrogenation in Water
Dachao Hong*, Yoshihiro Shimoyama, Yuji Ohgomori, Ryoichi Kanega, Hiroaki Kotani, Tomoya Ishizuka, Yoshihiro Kon, Yuichiro Himeda, and Takahiko Kojima
Inorg. Chem. 2020, 59, 17, 11976–11985
 

 

Probing Functionalities and Acidity of Calcined Phenylene-Bridged Periodic Mesoporous Organosilicates Using Dynamic Nuclear Polarization NMR, Diffuse Reflectance Infrared Fourier Transform Spectroscopy, and X-ray Photoelectron Spectroscopy
Cyril Pirez*, Hiroki Nagashima, Franck Dumeignil, and  Olivier Lafon*
J. Phys. Chem. C  2020, 124, 11, 6110-6120
 
 

 

 
DNP NMR spectroscopy of cross-linked organic polymers: rational guidelines towards optimal sample preparation

 

 

 


【2019】

 

Efficient Photocatalytic CO2 Reduction by a Ni(II) Complex Having Pyridine Pendants through Capturing a Mg2+ Ion as a Lewis-Acid Cocatalyst
Dachao Hong,Takuya Kawanishi,Yuto Tsukakoshi,Hiroaki Kotani,Tomoya Ishizuka,Takahiko Kojima*
J. Am. Chem. Soc.,  2019, 141, 20309-20317


 

Plasmonic Ag@TiO2 Core–Shell Nanoparticles for Enhanced CO2 Photoconversion to CH4
Dachao Hong*Lian-Ming Lyu, Kenji Koga, Yoshihiro Shimoyama, Yoshihiro Kon*
ACS Sustainable Chem. Eng., 2019, 7, 18955-18964
 



Nickel‐Catalyzed Selective Cross‐Coupling of Chlorosilanes with Organoaluminum Reagents
Yuki Naganawa*, Haiqing Guo, Kei Sakamoto, Yumiko Nakajima*
ChemCatChem, 2019, 11, 3756-3759
 

 

Mechanistic Insight into Synergistic Catalysis of Olefin Hydrogenation by a Hetero-Dinuclear RuII–CoII Complex with Adjacent Reaction Sites
Dachao Hong*, Yuji Ohgomori, Yoshihiro Shimoyama,Hiroaki Kotani, Tomoya Ishizuka, Yoshihiro Kon,Takahiko Kojima*
Inorg. Chem., 2019, 58, 11284-11288



Synthesis of hydrosilanes via Lewis-base-catalysed reduction of alkoxy silanes with NaBH4
Keiya Aoyagi, Yu Ohmori, Koya Inomata, Kazuhiro Matsumoto, Shigeru Shimada, Kazuhiko Sato  and Yumiko Nakajima*   
Chem. Commun., 2019, 55, 5859-5862




Direct Installation of a Silyl Linker on Ready-Made NHC Ligands: Immobilized NHC-Pd Complex for Buchwald–Hartwig Amination
Tomoteru Mizusaki,Kazuhiro Matsumoto,Katsuhiko Takeuchi,Norihisa Fukaya,Yukio Takagi,Jun-Chul Choi*
Organometallics, 2019, 38, 1872-1876

 

Heterogeneous hydrosilylation reaction catalysed by platinum complexes immobilized on bipyridine-periodic mesoporous organosilicas

 

 

[Pd(4-R3Si-IPr)(allyl)Cl], a Family of Silyl-Substituted Pd–NHC Complexes: Catalytic Systems for the Buchwald–Hartwig Amination
Norihisa Fukaya*, Tomoteru Mizusaki, Kouhei Hatakeyama, Yuto Seo, Yuuya Inaba, Kazuhiro Matsumoto, Vladimir Ya. Lee, Yukio Takagi, Junpei Kuwabara, Takaki Kanbara, Yoong-Kee Choe, Jun-Chul Choi*
Organometallics, 2019, 38, 375-384

 

2018年

 

Silica Support‐Enhanced Pd‐Catalyzed Allylation Using Allylic Alcohols
Ken Motokura,*  Marika Ikeda,  Minjune im,  Kiyotaka Nakajima, Sae Kawashima, Masayuki ambo, Wang‐Jae Chun, Shinji Tanaka
ChemCatChem 2018, 10, 4536–4544

 

 
Sequence‐Controlled Catalytic One‐Pot Synthesis of Siloxane Oligomers
Kazuhiro Matsumoto, Shigeru Shimada, Kazuhiko Sato
Chem. Eur.J.2019, 25,920 –928

 

 

Versatile etherification of alcohols with allyl alcohol by a titanium oxide-supported molybdenum oxide catalyst: gradual generation from titanium oxide and molybdenum oxide

 

Organocatalytic controlled/living ring-opening polymerization of cyclotrisiloxanes initiated by water with strong organic base catalysts


2017年

 

Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(ii) and its derivatives

 

By‐Product‐Free Siloxane‐Bond Formation and Programmed One‐Pot Oligosiloxane Synthesis
Kazuhiro Matsumoto, Kappam Veettil Sajna, Yasushi Satoh,Kazuhiko Sato, Shigeru Shimada*
Angew. Chem., Int. Ed., 2017, 56, 3168-3171

 

 

【書籍】

触媒化学融合研究センター職員が、執筆に関わった化学系書籍を紹介します。

 

有機合成のためのフロー化学
著者:F. Darvas 編、G. Dormán 編、V. Hessel 
小林 修 監訳・編著、小野澤 俊也 監訳・編著
出版年月日:2020/03/23
ISBN9784807909926
判型・ページ数:A5288ページ

 

酸化還元反応
著者日本化学会編・佐藤 一彦・北村 雅人著
シリーズ名:化学の要点シリーズ【1】巻
初版出版年月日:2012/1/30
ISBN:978-4-320-04406-7
判型・ページ数:B6・176ページ

 

 

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