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【発表論文:カバーピクチャー】  

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2023

 

Borane-Protecting Strategy for Hydrosilylation of Phosphorus-Containing Olefins
Yuki Naganawa*, Akira Fujita, Kei Sakamoto, Shinji Tanaka, Kazuhiko Sato, and Yumiko Nakajima*
ACS Omega 2023, 8, 6, 5672–5682
 

 

2022

 

 

Synthesis of Glycerol Carbonate from Glycerol and CO2 Using CaO as a Dehydrating Agent
Katsuhiko Takeuchi, Kazuhiro Matsumoto, Norihisa Fukaya, Kohtaro Osakada, Kazuhiko Sato, Jun-Chul Choi*
Asian Journal of Organic Chemistry, 2022, 11, e202200212.

 

 

Synthesis of organic carbamates as polyurethane raw materials from CO2: the quest for metal alkoxides as regenerable reagents
Katsuhiko Takeuchi, Kazuhiro Matsumoto, Norihisa Fukaya, Kazuhiko Sato, Jun-Chul Choi*
Dalton Transactions, 2022, 51, 15631-15643.

 

 

 

 

 

In situ formic acid dehydrogenation observation using a UV-vis-diffuse-reflectance spectroscopy system
Risheng Li, Tetsuya Kodaira*, and Hajime Kawanami*
Chemical Communications, 2022, 58 (79), 11021-11172

 

 

Asymmetric Dehydrative Cyclization of Allyl Alcohol to Cyclic Ether Using Chiral Brønsted Acid/CpRu(II) Hybrid Catalysts: A DFT Study of the Origin of Enantioselectivity
Manussada Ratanasak, Shinji Tanaka, Masato Kitamura*, and Jun-ya Hasegawa*
J. Org. Chem. 2022, 87, 19, 13062–13072

 

 

 
 
 
Laser Ablation Nanoarchitectonics of Au–Cu Alloys Deposited on TiO2 Photocatalyst Films for Switchable Hydrogen Evolution from Formic Acid Dehydrogenation
Dachao Hong*, Aditya Sharma, Dianping Jiang, Elena Stellino, Tomohiro Ishiyama, Paolo Postorino, Ernesto Placidi, Yoshihiro Kon, and Kenji Koga*
ACS Omega2022, 7, 35, 31260–31270
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Heterolytic cleavage of a Si–H bond by a metal–ligand cooperation of a cationic iridium amido complex and hydrosilylation of aldehydes

 

 

Production of lactic acid mediated by compressed carbon dioxide on heterogeneous Ni(ii) catalysts: a facile approach

 

2021

 

 

DNP NMR spectroscopy enabled direct characterization of polystyrene-supported catalyst species for synthesis of glycidyl esters by transesterification

 

 

 

Selectivity controlled transformation of carbon dioxide into a versatile bi-functional multi-carbon oxygenate using a physically mixed ruthenium–iridium catalyst

 

 

 

 

 

Aerobic oxygenation of α-methylene ketones under visible-light catalysed by a CeNi3 complex with a macrocyclic tris(salen)-ligand
 
 
 

 

 

N-Aryl and N-Alkyl Carbamates from 1 Atmosphere of CO2
Katsuhiko Takeuchi, Ming-Yu Chen, Hao-Yu Yuan, Hiroki Koizumi, Kazuhiro Matsumoto, Norihisa Fukaya, Yoong-Kee Choe, Shinji Shigeyasu, Seiji Matsumoto, Satoshi Hamura, Jun-Chul Choi*
Chem. Eur. J. 2021, 27, 18066-18073.

 

 

RuO2 Nanoparticle-Embedded Graphitic Carbon Nitride for Efficient Photocatalytic H2 Evolution
Yoshihiro Shimoyama, Kenji Koga, Hiroyasu Tabe, Yusuke Yamada, Yoshihiro Kon, Dachao Hong*
ACS Appl. Nano Mater. 2021, 4, 11, 11700–11708

 

 

Hydroxycarbonylation of alkenes with formic acid using a rhodium iodide complex and alkyl ammonium iodide
Masaki Okada, Katsuhiko Takeuchi, Kazuhiro Matsumoto, Tomoharu Oku, Jun-Chul Choi*
Org. Biomol. Chem. 2021, 19, 8727-8734

 

 

 

 
 
 
Bidentate Disilicate Framework for Bis-Grafted Surface Species (Chem. Eur. J. 47/2021)
Yusuke Ishizaka,Natsumi Arai,Dr. Kazuhiro Matsumoto,Dr. Hiroki Nagashima,Dr. Katsuhiko Takeuchi,Dr. Norihisa Fukaya,Dr. Hiroyuki Yasuda,Dr. Kazuhiko Sato,Dr. Jun-Chul Choi
Chem. Eur. J. 2021, 27, 12069-12077.

 

 


 

Hydrogen peroxide production from oxygen and formic acid by homogeneous Ir–Ni catalyst
Yoshihiro Shimoyama,  Yuji Ohgomori,  Yoshihiro Kon  and  Dachao Hong*
Dalton Trans., 2021, 50, 9410-9416      

 

 

 

Ammonia Combustion Catalysts
Satoshi Hinokuma * and Kazuhiko Sato
Chem. Lett. 2021, 50, 752–759

 

 

 

Metal–ligand cooperation behaviour of Fe and Co complexes bearing a tetradentate phenanthroline-based PNNP ligand

 

 

Direct Amidation of Esters and Amines under Continuous‐Flow Method
Md. Nurnobi Rashed,  Koichiro Masuda,  Tomohiro Ichitsuka,  Nagatoshi Koumura*,  Kazuhiko Sato*,  Shū Kobayashi*
Adv. Synth. Catal. 2021, 363, XXXX–XXXX; DOI: 10.1002/adsc.202001496).
 

 

Formate-driven catalysis and mechanism of an iridium–copper complex for selective aerobic oxidation of aromatic olefins in water

Treating octasilanol [Si8O12][OH]8 with tetramethoxysilane and trimethoxyvinylsilane: a halogen-free synthetic route to alkoxysilyl-substituted double-four-ring siloxanes

 

【2020】

 

Organocatalytic ring-opening polymerization of cyclotrisiloxanes using silanols as initiators for the precise synthesis of asymmetric linear polysiloxanes
 

 

Synthesis and Structure of Multinuclear Pd(II) Complexes Bridged by Phosphide or Azide Ligands
Katsuhiko Takeuchi, Kun-Woo Kim, Yong-Joo Kim*, Norihisa Fukaya, Kazuhiko Sato, and Jun-Chul Choi*
ACS Omega 2020, 5, 46, 29706–29713
 

 

Cooperative Effects of Heterodinuclear IrIII–MII Complexes on Catalytic H2 Evolution from Formic Acid Dehydrogenation in Water
Dachao Hong*, Yoshihiro Shimoyama, Yuji Ohgomori, Ryoichi Kanega, Hiroaki Kotani, Tomoya Ishizuka, Yoshihiro Kon, Yuichiro Himeda, and Takahiko Kojima
Inorg. Chem. 2020, 59, 17, 11976–11985
 

 

Probing Functionalities and Acidity of Calcined Phenylene-Bridged Periodic Mesoporous Organosilicates Using Dynamic Nuclear Polarization NMR, Diffuse Reflectance Infrared Fourier Transform Spectroscopy, and X-ray Photoelectron Spectroscopy
Cyril Pirez*, Hiroki Nagashima, Franck Dumeignil, and  Olivier Lafon*
J. Phys. Chem. C  2020, 124, 11, 6110-6120
 
 

 

 
DNP NMR spectroscopy of cross-linked organic polymers: rational guidelines towards optimal sample preparation

 

 

 


【2019】

 

Efficient Photocatalytic CO2 Reduction by a Ni(II) Complex Having Pyridine Pendants through Capturing a Mg2+ Ion as a Lewis-Acid Cocatalyst
Dachao Hong,Takuya Kawanishi,Yuto Tsukakoshi,Hiroaki Kotani,Tomoya Ishizuka,Takahiko Kojima*
J. Am. Chem. Soc.,  2019, 141, 20309-20317


 

Plasmonic Ag@TiO2 Core–Shell Nanoparticles for Enhanced CO2 Photoconversion to CH4
Dachao Hong*Lian-Ming Lyu, Kenji Koga, Yoshihiro Shimoyama, Yoshihiro Kon*
ACS Sustainable Chem. Eng., 2019, 7, 18955-18964
 



Nickel‐Catalyzed Selective Cross‐Coupling of Chlorosilanes with Organoaluminum Reagents
Yuki Naganawa*, Haiqing Guo, Kei Sakamoto, Yumiko Nakajima*
ChemCatChem, 2019, 11, 3756-3759
 

 

Mechanistic Insight into Synergistic Catalysis of Olefin Hydrogenation by a Hetero-Dinuclear RuII–CoII Complex with Adjacent Reaction Sites
Dachao Hong*, Yuji Ohgomori, Yoshihiro Shimoyama,Hiroaki Kotani, Tomoya Ishizuka, Yoshihiro Kon,Takahiko Kojima*
Inorg. Chem., 2019, 58, 11284-11288



Synthesis of hydrosilanes via Lewis-base-catalysed reduction of alkoxy silanes with NaBH4
Keiya Aoyagi, Yu Ohmori, Koya Inomata, Kazuhiro Matsumoto, Shigeru Shimada, Kazuhiko Sato  and Yumiko Nakajima*   
Chem. Commun., 2019, 55, 5859-5862




Direct Installation of a Silyl Linker on Ready-Made NHC Ligands: Immobilized NHC-Pd Complex for Buchwald–Hartwig Amination
Tomoteru Mizusaki,Kazuhiro Matsumoto,Katsuhiko Takeuchi,Norihisa Fukaya,Yukio Takagi,Jun-Chul Choi*
Organometallics, 2019, 38, 1872-1876

 

Heterogeneous hydrosilylation reaction catalysed by platinum complexes immobilized on bipyridine-periodic mesoporous organosilicas

 

 

[Pd(4-R3Si-IPr)(allyl)Cl], a Family of Silyl-Substituted Pd–NHC Complexes: Catalytic Systems for the Buchwald–Hartwig Amination
Norihisa Fukaya*, Tomoteru Mizusaki, Kouhei Hatakeyama, Yuto Seo, Yuuya Inaba, Kazuhiro Matsumoto, Vladimir Ya. Lee, Yukio Takagi, Junpei Kuwabara, Takaki Kanbara, Yoong-Kee Choe, Jun-Chul Choi*
Organometallics, 2019, 38, 375-384

 

2018年

 

Silica Support‐Enhanced Pd‐Catalyzed Allylation Using Allylic Alcohols
Ken Motokura,*  Marika Ikeda,  Minjune im,  Kiyotaka Nakajima, Sae Kawashima, Masayuki ambo, Wang‐Jae Chun, Shinji Tanaka
ChemCatChem 2018, 10, 4536–4544

 

 
Sequence‐Controlled Catalytic One‐Pot Synthesis of Siloxane Oligomers
Kazuhiro Matsumoto, Shigeru Shimada, Kazuhiko Sato
Chem. Eur.J.2019, 25,920 –928

 

 

Versatile etherification of alcohols with allyl alcohol by a titanium oxide-supported molybdenum oxide catalyst: gradual generation from titanium oxide and molybdenum oxide

 

Organocatalytic controlled/living ring-opening polymerization of cyclotrisiloxanes initiated by water with strong organic base catalysts


2017年

 

Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(ii) and its derivatives

 

By‐Product‐Free Siloxane‐Bond Formation and Programmed One‐Pot Oligosiloxane Synthesis
Kazuhiro Matsumoto, Kappam Veettil Sajna, Yasushi Satoh,Kazuhiko Sato, Shigeru Shimada*
Angew. Chem., Int. Ed., 2017, 56, 3168-3171

 

 

【書籍】

触媒化学融合研究センター職員が、執筆に関わった化学系書籍を紹介します。

 

有機合成のためのフロー化学
著者:F. Darvas 編、G. Dormán 編、V. Hessel 
小林 修 監訳・編著、小野澤 俊也 監訳・編著
出版年月日:2020/03/23
ISBN9784807909926
判型・ページ数:A5288ページ

 

酸化還元反応
著者日本化学会編・佐藤 一彦・北村 雅人著
シリーズ名:化学の要点シリーズ【1】巻
初版出版年月日:2012/1/30
ISBN:978-4-320-04406-7
判型・ページ数:B6・176ページ

 

 

【ポスドク就職先等】

学生・ポスドク等の就職先をご紹介します。(順不同)

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